An aromatic amine used as a component of oxidative hair dyes.
What it is
p-Phenylenediamine (benzene-1,4-diamine, also known as PPD) is an aromatic amine used as a primary intermediate in oxidative hair dyes. CosIng lists it as a hair-dyeing ingredient and also gives it the Colour Index number CI 76060.
Where it is used
Found in permanent hair colours and other oxidative hair dye products.
Limits of interpretation
The INCI list shows which ingredients are present, not how much of each. Above 1%, ingredients are listed in descending order of weight; below 1% the order is free.
The label does not show its concentration or which other dye components it is combined with.
Functions
- Hair dyeing
- Imparting color to hair. Hair dyeing preparations may be temporary, semi-permanent, permanent, depending on the length of time the colorant remains on the hair.
EU regulation
- Product type
- Hair dye substance in oxidative hair dye products
- Conditions and warnings
- (a) To be printed on the label: The mixing ratio. ‘ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporary “black henna” tattoos may increase your risk of allergy. Do not colour your hair if: — you have a rash on your face or sensitive, irritated and damaged scalp, — you have ever experienced any reaction after colouring your hair, — you have experienced a reaction to a temporary “black henna” tattoo in the past. Contains phenylenediamines. Do not use to dye eyelashes or eyebrows.’ (b) To be printed on the label: The mixing ratio. ‘For professional use only. Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporary “black henna” tattoos may increase your risk of allergy. Do not colour your hair if: — you have a rash on your face or sensitive, irritated and damaged scalp, — you have ever experienced any reaction after colouring your hair, — you have experienced a reaction to a temporary “black henna” tattoo in the past. Contains phenylenediamines. Wear suitable gloves.’
- As of
- 3 November 2026 · (EC) 2013/344
Safety Gate alerts (EU)
32 alerts about dangerous cosmetics in the EU mention this substance. An alert concerns a specific product, usually one that breaks EU rules.
- Polar Hair Care – Red Hair Dye Shampoo (2026-10-21)
- Polar Hair Care – Dark Brown Hair Dye Shampoo (2026-10-15)
- Polar Hair Care – Black Hair Dye Shampoo (2026-10-15)
- Hairfiller – Instant Dye Shampoo Dark Brown (2026-09-28)
- Hairfiller – Hairfiller Instant Dye Shampoo Black (2026-09-28)
Scientific opinions (SCCS)
- Hydroxypropyl p-phenylenediamine and its dihydrochloride salt (A165)
- Addendum to the scientific Opinion SCCS/1491/12 on the hair dye substance 2-Methoxy-methyl-p-phenylenediamine and its sulfate salt - COLIPA n° A160 - Submission II – use on eyelashes
- N,N'-Bis-(2-hydroxyethyl)-2-nitro-p-phenylenediamine (B34)
Opinions of the EU Scientific Committee on Consumer Safety that mention this ingredient. They assess specific uses and concentrations; read the opinion for its scope.
Products with this ingredient (11)
- Black Hair Dye Shampoo · Meidu
- Revlon ColorSilk Beautiful Color Saç Boyası 73 Şampanya Sarısı · REVLON
- Revlon ColorSilk Beautiful Color Saç Boyası 44 Orta Kızıl Kahve · REVLON
- Nice 'n Easy Root Touch-Up Permanent Hair Color, 4R Dark Auburn · Clairol
- Revlon ColorSilk Beautiful Color Saç Boyası 51 Açık Kahve · REVLON
- Paris Superior Preference 5CB Medium Chestnut Brown Warmer Haircolor · L'Oréal
- Color Advance negro nº1 · Llongueras
- Revlon ColorSilk Beautiful Color Saç Boyası 55 Açık Kızıl Kahve · REVLON
- Perfect Intensive Color Creme 180 Cyclamen · Venita
- Cameleo Blond Moyen 7.0 · Delia
- Colorsilk Beautiful Color - 32 Acajou foncé · Colorsilk

